AB
Liquid oxygen (O at below −183 °C)
Oxygen
AllotropesO, O (ozone) and more (see Allotropes of oxygen)
Appearancegas: colorless
liquid and solid: pale blue
Standard atomic weight A °(O)
• [15.999 03 , 15.999 77] 1
• 15.999 ± 0.001 (abridged) 2
Oxygen in the periodic table


O

S nitrogen ← oxygen → fluorine
Atomic number (Z)8
Groupgroup 16 (chalcogens)
Periodperiod 2
Blockp-block
Electron configuration[He] 2s 2p
Electrons per shell2, 6
Physical properties
Phase at STPgas
Melting point(O) 54.36 K ​(−218.79 °C, ​−361.82 °F)
Boiling point(O) 90.188 K ​(−182.962 °C, ​−297.332 °F)
Density (at STP)1.429 g/L
when liquid (at b.p.)1.141 g/cm
Triple point54.361 K, ​0.1463 kPa
Critical point154.581 K, 5.043 MPa
Heat of fusion(O) 0.444 kJ/mol
Heat of vaporization(O) 6.82 kJ/mol
Molar heat capacity14.689 J/(mol·K) (O)
29.378 J/(mol·K) (O)
Specific heat capacity918.12 J/(kg·K) (O)
Vapor pressure
Atomic properties
Oxidation statescommon: −2
−1,3 0, +1,3 +23
ElectronegativityPauling scale: 3.44
Ionization energies• 1st: 1313.9 kJ/mol
• 2nd: 3388.3 kJ/mol
• 3rd: 5300.5 kJ/mol
• (more)
Covalent radius66±2 pm
Van der Waals radius152 pm
Spectral lines of oxygen
Other properties
Natural occurrenceprimordial
Crystal structure​cubic (cP16)
Lattice constanta = 678.28 pm (at t.p.)4
Thermal conductivity26.58×10 W/(m⋅K)
Magnetic orderingparamagnetic
Molar magnetic susceptibility+3449.0×10 cm/mol (293 K)5
Speed of sound330 m/s (gas, at 27 °C)
CAS Number7782-44-7
History
Namingfrom the Greek ὀξύς (acid, literally ‘sharp’, from the taste of acids) and -γενής (producer)
DiscoveryMichael Sendivogius
Carl Wilhelm Scheele (1604, 1771)
Named byAntoine Lavoisier (1777)
Isotopes of oxygen

Oxygen, O

(echo:: @ )

Footnotes

  1. “Standard Atomic Weights: Oxygen”. CIAAW. 2009.

  2. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (May 4, 2022). “Standard atomic weights of the elements 2021 (IUPAC Technical Report)”. Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.

  3. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 28. doi:10.1016/C2009-0-30414-6. ISBN 978-0-08-037941-8. 2 3

  4. Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.

  5. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.